On the Integrations tab, click on Enable button below GoToWebinar icon.

A pop-up window will open that will prompt you to enter the login details of your GoToWebinar account. After accomplishing the details asked, click on Allow button.

You can disable GoToWebinar on your app by clicking Disable button, or edit your account information by clicking Edit. Don't forget to click Save (found on the upper right) after every change you made.